Vinicius Junior was sent off amid a late brawl as Real Madrid fell to a 1-0 loss against Valencia in an ill-tempered LaLiga encounter.
The Brazil winger had already been at the centre of another flashpoint earlier in the game, following a bizarre incident involving two balls on the pitch at Mestalla.
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Diego Lopez's lone goal helped Los Che continue their resurgent form as they seek to secure top-flight safety in the final weeks of the season.
But for Carlo Ancelotti's visitors - fresh from a chastening Champions League exit against Manchester City - it marked a miserable return to domestic duty.